Ruthenium-catalyzed reductive coupling between ketones and primary alcohols in the presence of ethylenediamine

被引：15

作者：

Cho, Chan Sik ^{[1
]}

机构：

[1] Kyungpook Natl Univ, Res Inst Ind Technol, Taegu 702701, South Korea

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 267卷 / 1-2期

关键词：

carbon-carbon coupling; ethylenediamine; ketones; primary alcohols; ruthenium catalyst; secondary alcohols;

D O I：

10.1016/j.molcata.2006.11.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ketones are reductively coupled with an array of primary alcohols in dioxane at 80 degrees C in the presence of a catalytic amount of a ruthenium catalyst along with KOH and ethylenediamine to give the corresponding carbon-carbon coupled secondary alcohols in moderate to good yields. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：49 / 52

页数：4

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