Oxidation catalysis of a manganese(III)porphyrin intercalated in layered double hydroxide clays

被引：46
|
作者：
Tong, ZW
Shichi, T
Takagi, K [1 ]
机构：
[1] Nagoya Univ, Dept Crystalline Mat Sci, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[2] JST, CREST, Tokyo, Japan
来源：
MATERIALS LETTERS | 2003年 / 57卷 / 15期
关键词：
layered double hydroxide; tetra(p-ulfonatophenyl)porphinatomanganese(III) anion; intercalation; catalysts; nanocomposites;
D O I：
10.1016/S0167-577X(02)01206-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Tetra(p-sulfonatophenyl)porphinatomanganese(III) anions, [Mn(III)TSPPCl](4-) were intercalated into the interlayer spaces of Mg-Al-layered double hydroxide (LDH) and studied as a catalyst for the oxidation of 2,4,6-trichlorophenol (TCP). The Mn(III)TSPP anions could be efficiently intercalated into the LDH interlayers as a perpendicular Mn(III)TSPP/LDH complex by adsorbing the guest molecules, which is a characteristic for easy handling and a high catalytic activity. (C) 2002 Elsevier Science B.V. All rights reserved.
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收藏
页码：2258 / 2261
页数：4
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