Preparation of layered phosphatoantimonic acid-intercalated manganese porphyrin and catalytic oxidation of simmulated cytochrome

被引：0

作者：

Hu, XM ^{[1
]}

Pi, ZX ^{[1
]}

Mei, ZQ ^{[1
]}

Gu, GB ^{[1
]}

Huang, ZT ^{[1
]}

机构：

[1] S CHINA UNIV TECHNOL,DEPT CHEM ENGN,GUANGZHOU 510641,PEOPLES R CHINA

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 1996年 / 17卷 / 09期

关键词：

manganese porphyrin; layered phosphatoantimonic acid; intercalation; catalytic behaviour;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese tetraphenylporphyrin as a guest molecule was intercalated in situ into the layered host material phosphatoantimonic acid. The porphyrin immobilized in the layered structure exhibits a fairly catalytic capability for the epoxidation of cyclohexene and the oxidation of n-octane by hydrogen peroxide, due to the prevention of the formation of mu-dimers.

引用

页码：1353 / 1355

页数：3