Blockage of rigid-rod β-barrel pores with rigid-rod α-helix mimics

被引：14

作者：

Litvinchuk, S ^{[1
]}

Matile, S ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 1-2期

关键词：

barrel-stave supramolecules; lipid bilayer membranes; molecular recognition; self-assembly; synthetic multifunctional pores;

D O I：

10.1080/10610270412331328952

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the completion of a series of biological beta-barrel pores blocked by an alpha-helix (Oomen et al., EMBO J. 2004, 23, 1257) and rigid-rod beta-barrel pores blocked by an alpha-helix (Sorde and Matile, J. Supramol. Chem. 2002,2,191) with experimental evidence for a rigid-rod beta-barrel pore blocked by a rigid-rod alpha-helix mimic. These presumably dimeric, shape-persistent p-oligophenyl alpha-helix mimics are of interest to address the functional-group density of full alpha-helix surfaces and to obtain insights into alpha-helix folding and recognition.

引用

页码：135 / 139

页数：5

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