A boron-based electrolyte additive for calcium electrodeposition

被引：17
|
作者：
Forero-Saboya, Juan [1 ]
Bodin, Charlotte [1 ,2 ]
Ponrouch, Alexandre [1 ,2 ]
机构：
[1] ICMAB CSIC, Inst Ciencia Mat Barcelona, Campus UAB, Bellaterra 08193, Spain
[2] European Res Inst, ALISTORE, CNRS FR 3104, F-80039 Amiens, France
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2021年 / 124卷
基金：
欧洲研究理事会;
关键词：
Calcium batteries; Boron-containing additive; Calcium plating; Metal anode;
D O I：
10.1016/j.elecom.2021.106936
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In recent years, several organic electrolytes have been reported allowing calcium metal electrodeposition. In all cases, some degree of passivation on the surface of the calcium electrode was reported. Following a recent report on based passivation layer playing a crucial role for Ca plating in electrolyte solutions containing Ca(BF4)(2), here we report the use of a boron-containing additive. The presence of this additive allows Ca plating and stripping using a Ca(TFSI)(2) containing electrolyte, which otherwise lead to the formation of a fully Ca2+ blocking passivation layer.
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页数：5
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