Chiroptical switches and sensors based on ligand conformational changes in labile coordination complexes

被引：0

作者：

Canary, JW ^{[1
]}

Zahn, S ^{[1
]}

Chiu, YH ^{[1
]}

dos Santos, O ^{[1
]}

Liu, J ^{[1
]}

Zhu, L ^{[1
]}

机构：

[1] NYU, Dept Chem, New York, NY 10003 USA

来源：

ENANTIOMER | 2000年 / 5卷 / 3-4期

关键词：

circular dichroism; conformation; coordination complex; absolute configuration; molecular electronics; sensor;

D O I：

暂无

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A series of molecules have been developed that give significantly differentiated circular dichroic signals upon presentation of a metal ion, exchange of metal ion, or change in oxidation state. These properties have led to prototypes of molecular sensors for metal ions and redox-mediated chiroptical switches. In some complexes, the CD signal arises by an excitonic coupling mechanism, affording further information about ligand conformation or absolute configuration.

引用

页码：397 / 403

页数：7

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