Light Switches the Ligand! Photochromic Azobenzene-Phosphanes

被引：37
|
作者：
Dolores Segarra-Maset, Maria [1 ]
van Leeuwen, Piet W. N. M. [1 ]
Freixa, Zoraida [1 ]
机构：
[1] ICIQ, Inst Chem Res Catalonia, Tarragona 43007, Spain
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 14期
关键词：
P ligands; Molecular switches; Azo compounds; Ligand effects; Homogeneous catalysis; RHODIUM-CATALYZED HYDROSILYLATION; CONTAINING PHOSPHINE COMPLEXES; BOWL-SHAPED PHOSPHINE; MOLECULAR-STRUCTURE; STRUCTURAL-CHARACTERIZATION; RATE ENHANCEMENT; METAL-COMPLEXES; CRYSTAL; PALLADIUM(II); TRIARYLPHOSPHINES;
D O I：
10.1002/ejic.201000063
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three phosphanes containing azobenzene groups were synthesized, and the photochemical behaviour of their platinum complexes was studied by using the light-induced (E)/(Z) isomerization as a switch to change ligand properties.
引用
收藏
页码：2075 / 2078
页数：4
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