Low-temperature magnets M[N(CN)2]2(pyrimidine) (M = Fe and Co) with a 3-D network

被引:47
|
作者
Kusaka, T [1 ]
Ishida, T [1 ]
Hashizume, D [1 ]
Iwasaki, F [1 ]
Nogami, T [1 ]
机构
[1] Univ Electrocommun, Chofu, Tokyo 1828585, Japan
关键词
D O I
10.1246/cl.2000.1146
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
X-Ray crystal structure analyses reveal that the title complexes have a 3-D network, in which N(CN)(2)(-) and pyrimidine contribute mu -1,5-bridged 2-D and mu -1,3-bridged 1-D structures, respectively. Magnetic measurements indicate that the Fe and Co complexes have spontaneous magnetizations below the transition temperatures of 3.2 and 1.8 K, respectively.
引用
收藏
页码:1146 / 1147
页数:2
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