The solubility of C-60 in organic and inorganic solvents

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作者
Beck, MT
Mandi, G
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
The solubility of C-60 in 60 different organic and 7 inorganic liquids at room temperature is given. Although certain tendencies between single solvent parameters and the solubilities are evident, a generally valid correlation can be imagined in a multiparameter space. All the meaningful evidence indicate that C-60 is monomeric in all solvents. The aggregate formation concluded from light-scattering experiments are probably an artifact due to the non-linear optical behavior of the solutions. The great differences in some of the experimentally determined solubilities of C-60 in the same solvent may be caused by phase transformation due to mechano- or sonochemical effects.
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页码:32 / 38
页数:7
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