Two-dimensional infrared spectroscopy of vibrational polaritons of molecules in an optical cavity

被引：56
|
作者：
Saurabh, Prasoon [1 ]
Mukamel, Shaul [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 2016年 / 144卷 / 12期
基金：
美国国家科学基金会;
关键词：
AMIDE-I; MODES; SCATTERING; EXCITONS; WEAK;
D O I：
10.1063/1.4944492
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Strong coupling of molecular vibrations to an infrared cavity mode affects their nature by creating dressed polariton states. We show how the single and double vibrational polariton manifolds may be controlled by varying the cavity coupling strength and probed by a time domain two-dimensional infrared (2DIR) technique, double quantum coherence. Applications are made to the amide-I (CO) and amide-II (CN) bond vibrations of N-methylacetamide. (C) 2016 AIP Publishing LLC.
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页数：7
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