Na-CaO/MgO dolomites used as heterogeneous catalysts in canola oil transesterification for biodiesel production

被引:21
|
作者
Murguia-Ortiz, D. [1 ]
Cordova, I. [1 ]
Manriquez, M. E. [1 ]
Ortiz-Islas, E. [2 ]
Cabrera-Sierra, R. [1 ]
Contreras, J. L. [3 ]
Alcantar-Vazquez, B. [4 ]
Trejo-Rubio, M. [1 ]
Vazquez-Rodriguez, J. T. [1 ]
Castro, L. V. [1 ]
机构
[1] UPALM, Inst Politecn Nacl, ESIQIE, Cdmx 07738, Mexico
[2] Inst Nacl Neurol & Neurocirug, Lab Nanotecnol, Insurgentes Sur 3877, Cdmx 14269, Mexico
[3] UAM A, Dept Energia, Ave Sn Pablo 180, Cdmx 02200, Mexico
[4] UNAM, Inst Ingn, Ave Univ 3000, Cdmx 04510, Mexico
关键词
Transesterification; Biodiesel; Dolomite; Optimization; OXIDE CATALYSTS;
D O I
10.1016/j.matlet.2021.129587
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mexican dolomites were doped with sodium nitrate and calcined at 900 degrees C to generate the corresponding CaO/MgO and Na-CaO/MgO mixed metal oxides. The resulting oxides were tested with regard to the catalytic transesterification of commercial canola oil in a batch reactor for biodiesel production. The catalysts were characterized using several spectroscopic and physicochemical techniques. Among all catalysts, Na-CaO/MgO effected the highest conversion rate, at 95.4%. The experimental catalytic parameters were processed in a nonlinear program to obtain the optimal theoretical conversion rate of 97.46%, consistent with the experimental results. (c) 2021 Elsevier B.V. All rights reserved.
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页数:4
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