Cobalt(II) and iron(II) bis(2,2′: 6′,2"-terpyridine) complexes functionalized with alkynes and cobalt carbonyl clusters

被引:10
|
作者
Constable, EC
Hart, CP
Housecroft, CE
机构
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
[2] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England
关键词
2,2 ': 6 ',2 ''-terpyridine; cobalt(II); iron(II); carbonyl cluster; alkyne;
D O I
10.1002/aoc.435
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The preparation and characterization of new cobalt(II) and iron(II) complexes containing alkyne or cobalt cluster functionalized 2,2': 6',2"-terpyridine ligands are described. The cobalt(II) complexes exhibit paramagnetically shifted, but well-resolved, H-1 NMR spectra that are characteristic of low-spin cobalt(II) solution species. Copyright (C) 2003 John Wiley Sons, Ltd.
引用
收藏
页码:383 / 387
页数:5
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