Cobalt(II) and iron(II) bis(2,2′: 6′,2"-terpyridine) complexes functionalized with alkynes and cobalt carbonyl clusters

被引：10
|
作者：
Constable, EC
Hart, CP
Housecroft, CE
机构：
[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland
[2] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 6-7期
关键词：
2,2 ': 6 ',2 ''-terpyridine; cobalt(II); iron(II); carbonyl cluster; alkyne;
D O I：
10.1002/aoc.435
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The preparation and characterization of new cobalt(II) and iron(II) complexes containing alkyne or cobalt cluster functionalized 2,2': 6',2"-terpyridine ligands are described. The cobalt(II) complexes exhibit paramagnetically shifted, but well-resolved, H-1 NMR spectra that are characteristic of low-spin cobalt(II) solution species. Copyright (C) 2003 John Wiley Sons, Ltd.
引用
收藏
页码：383 / 387
页数：5
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