Unusual Metal-Coordinated Zwitterionic P-C-N-C-N-C Phosphido Adducts

被引：6

作者：

Ekubo, Allen T. ^{[1
]}

Elsegood, Mark R. J. ^{[1
]}

Lake, Andrew J. ^{[1
]}

Smith, Martin B. ^{[1
]}

机构：

[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 08期

基金：

英国工程与自然科学研究理事会;

关键词：

PHOSPHENIUM COMPLEXES; CHEMISTRY; LIGANDS; CATIONS; PTA; PALLADIUM(II); ANALOGS; IONS;

D O I：

10.1021/ic1002308

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rare examples of homodinuclear zwitterionic Pd-II and Pt-II complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN-(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.

引用

页码：3703 / 3705

页数：3

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