Unusual Metal-Coordinated Zwitterionic P-C-N-C-N-C Phosphido Adducts

被引：6
|
作者：
Ekubo, Allen T. [1 ]
Elsegood, Mark R. J. [1 ]
Lake, Andrew J. [1 ]
Smith, Martin B. [1 ]
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 08期
基金：
英国工程与自然科学研究理事会;
关键词：
PHOSPHENIUM COMPLEXES; CHEMISTRY; LIGANDS; CATIONS; PTA; PALLADIUM(II); ANALOGS; IONS;
D O I：
10.1021/ic1002308
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Rare examples of homodinuclear zwitterionic Pd-II and Pt-II complexes with bridging, two-coordinate P{cyclo-CH2N(R)CHN-(R)CH2} ligands (R = 4-FC6H4CH2, C6H5CH2) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.
引用
收藏
页码：3703 / 3705
页数：3
相关论文
共 50 条
  • [1] Sequential electrophilic P-C bond formation in metal-coordinated chlorophosphines
    Jayaraman, Arumugam
    Jacob, Tyler V.
    Bisskey, Jeff
    Sterenberg, Brian T.
    DALTON TRANSACTIONS, 2015, 44 (19) : 8788 - 8791
  • [2] Metal-assisted electrocyclic reaction in a C=N-N=C-C=N system
    Pal, PK
    Chowdhury, S
    Drew, MGB
    Datta, D
    NEW JOURNAL OF CHEMISTRY, 2000, 24 (12) : 931 - 933
  • [3] ADDUCTS OF DIMETHYLKETENE WITH C=N CONTAINING COMPOUNDS
    MARTIN, JC
    HOYLE, VA
    BRANNOCK, KC
    TETRAHEDRON LETTERS, 1965, (40) : 3589 - &
  • [4] New Approaches to Functionalizing Metal-Coordinated N2
    Andino, Jose G.
    Mazumder, Shivnath
    Pal, Kuntal
    Caulton, Kenneth G.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (18) : 4726 - 4732
  • [5] Density functional exploration of C=C, N=N and P=P bonds.
    Brunello, SC
    Challa, JR
    Simpson, MC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1014 - U1014
  • [6] Hydrocarbon C-H oxidation by self-folded metal-coordinated cavitands
    Mettry, Magi
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [7] Regioselective C-N bond cleavage in an η2(N,C)-coordinated pyridine and an η1(N) -&gt η2(N,C) bonding rearrangement in coordinated quinoline. Models for hydrodenitrogenation catalysis
    Gray, Steven D.
    Smith, David P.
    Bruck, Michael A.
    Wigley, David E.
    Journal of the American Chemical Society, 1992, 114 (13):
  • [8] Organocatalysis of C=N/C=N and C=C/C=N Exchange in Dynamic Covalent Chemistry
    Wilhelms, Nadine
    Kulchat, Sirinan
    Lehn, Jean-Marie
    HELVETICA CHIMICA ACTA, 2012, 95 (12) : 2635 - 2651
  • [9] Three new phosphoric triamides with a [C(O)NH]P(0)[N(C)(C)]2 skeleton: a database analysis of C-N-C and P-N-C bond angles
    Pourayoubi, Mehrdad
    Tarahhomi, Atekeh
    Rheingold, Arnold L.
    Golen, James A.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2014, 70 : 998 - U286
  • [10] Stoichiometric variation in C:N, C:P, and N:P ratios of littoral benthic invertebrates
    Liess, A
    Hillebrand, H
    JOURNAL OF THE NORTH AMERICAN BENTHOLOGICAL SOCIETY, 2005, 24 (02): : 256 - 269
12345