Rhodium-catalyzed enantioselective hydrogenation using chiral monophosphonite ligands

被引：137
|
作者：
Reetz, MT [1 ]
Sell, T [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 33期
关键词：
enantioselection; reduction; rhodium and compounds; phosphorus compounds; amino acids and derivatives;
D O I：
10.1016/S0040-4039(00)01099-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Surprisingly high enantioselectivities in the Rh-catalyzed hydrogenation of itaconic acid dimethyl eater and methyl-2-acetamido acrylate are observed upon using chiral monophosphonite ligands derived from binaphthol (ee up to 94%). Although appropriate chelating diphosphonites are more effective, the easy modular synthesis of the chiral monophosphonites may allow for the optimization of a given asymmetric hydrogenation reaction. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：6333 / 6336
页数：4
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