Synthesis and Anion Binding Properties of Diamide Derivatives of p-tert-Butylcalix[4]arene

被引:5
|
作者
Kendi, Burcu [1 ]
Naziroglu, Hayriye Nevin [2 ]
Yilmaz, Mustafa [1 ]
Sirit, Abdulkadir [1 ]
机构
[1] Selcuk Univ, Dept Chem, TR-42099 Konya, Turkey
[2] Karamanoglu Mehmetbey Univ, Dept Chem, TR-70100 Karaman, Turkey
关键词
Anion recognition; amide; calix[4]arene; tetrabutylammonium salt; MOLECULAR RECOGNITION; RECEPTORS; AMIDE; COMPLEXATION; PHOSPHATE; HOST; EXTRACTION; MEMBRANE; CHARGE;
D O I
10.1080/10601320903526923
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Two novel calix[4]arene based anion receptors containing positively charged binding sites in combination with amide groups have been synthesized. Anion binding properties of these receptors towards H2PO4- and HSO4- ions were studied by 1H-NMR spectroscopy and the results reflected that receptor 5 selectively recognize H2PO4- in preference to HSO4- ions. The molar ratio and the association constants of the complexes were determined by using Job plots and a nonlinear least-squares fitting method, respectively.
引用
收藏
页码:225 / 229
页数:5
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