Synthesis and Anion Binding Properties of Diamide Derivatives of p-tert-Butylcalix[4]arene

被引：5

作者：

Kendi, Burcu ^{[1
]}

Naziroglu, Hayriye Nevin ^{[2
]}

Yilmaz, Mustafa ^{[1
]}

Sirit, Abdulkadir ^{[1
]}

机构：

[1] Selcuk Univ, Dept Chem, TR-42099 Konya, Turkey

[2] Karamanoglu Mehmetbey Univ, Dept Chem, TR-70100 Karaman, Turkey

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2010年 / 47卷 / 03期

关键词：

Anion recognition; amide; calix[4]arene; tetrabutylammonium salt; MOLECULAR RECOGNITION; RECEPTORS; AMIDE; COMPLEXATION; PHOSPHATE; HOST; EXTRACTION; MEMBRANE; CHARGE;

D O I：

10.1080/10601320903526923

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two novel calix[4]arene based anion receptors containing positively charged binding sites in combination with amide groups have been synthesized. Anion binding properties of these receptors towards H2PO4- and HSO4- ions were studied by 1H-NMR spectroscopy and the results reflected that receptor 5 selectively recognize H2PO4- in preference to HSO4- ions. The molar ratio and the association constants of the complexes were determined by using Job plots and a nonlinear least-squares fitting method, respectively.

引用

页码：225 / 229

页数：5

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