Baeyer-Villiger oxidation of ketones with hydrogen peroxide catalyzed by cellulose-supported dendritic Sn complexes

被引：32
|
作者：
Li, Cuilin [1 ]
Wang, Jiaqing [1 ]
Yang, Zhiwang [1 ]
Hu, Zhongai [1 ]
Lei, Ziqiang [1 ]
机构：
[1] NW Normal Univ, Key Lab Polymer Mat Gansu Prov, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
来源：
CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 08期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
Baeyer-Villiger oxidation; cellulose-supported dendrimer; hydrogen peroxide; solid phase synthesis;
D O I：
10.1016/j.catcom.2006.11.012
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cellulose supported dendritic Sn complexes were prepared by solid phase synthetic methodology. A series of cycloketones and acyclic ketones including 2-andamantanone, cyclohexanone, 4-methylcyclohexanone, 4-tert-butylcyclohexanone, 3-methyl-2-pentanone, 4-methyl-2-pentanone and cyclopentanone were oxidized by hydrogen peroxide in a reaction catalyzed by cellulose-supported dendritic Sri complexes, affording the corresponding lactones or esters with the conversion of 70-99% and the product selectivity of 100%. The catalysts can be recycled for several times without any significant decline in catalytic activity. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：1202 / 1208
页数：7
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