Redox Isomerism of α-Ferrocenylcarbenium Ions

被引：6

作者：

Fomin, V. M. ^{[1
]}

Kochetkova, K. S. ^{[1
]}

Klyuchevskii, K. V. ^{[1
]}

机构：

[1] NI Lobachevskii State Univ Nizhny Novgorod, Pr Gagarina 23, Nizhnii Novgorod 603950, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2018年 / 88卷 / 05期

关键词：

ferrocenylmethanol; vinylferrocene; protonation; alpha-ferrocenylcarbenium ion; ferrocenium cation; redox isomerism; FERROCENYLACETIC ACID; ORGANIC-SOLVENTS; OXIDATION; STABILIZATION; PEROXIDES; FERROCENE;

D O I：

10.1134/S1070363218050183

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of alpha-ferrocenylcarbenium ions FcC(+)H(2) (lambda (max) 600 nm) and FcC(+)HCH(3) (lambda (max) 730 nm) and their redox isomerism at the protonation of ferrocenylmethanol and vinylferrocene was proved using the method of electronic spectroscopy. The effect on the process of the solvent and acid nature as well as of hydrogen peroxide additives is discussed.

引用

页码：948 / 953

页数：6

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