Hydrophobic encapsulation of hydrocarbon gases

被引：18
|
作者：
Leontiev, Alexander V. [1 ]
Saleh, Anas W. [1 ]
Rudkevich, Dmitry M. [1 ]
机构：
[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 09期
关键词：
D O I：
10.1021/ol070465v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Encapsulation data for hydrophobic hydrocarbon gases within a water-soluble hemicarcerand in aqueous solution are reported. It is concluded that hydrophobic interactions serve as the primary driving force for the encapsulation, which can be used for the design of gas-separating polymers with intrinsic inner cavities.
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页码：1753 / 1755
页数：3
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