New Trends in Oxidative Functionalization of Carbon-Hydrogen Bonds: A Review

被引：168
|
作者：
Shul'pin, Georgiy B. [1 ,2 ]
机构：
[1] Russian Acad Sci, Semenov Inst Chem Phys, Dept Kinet & Catalysis, Dom 4, Moscow 119991, Russia
[2] Plekhanov Russian Univ, Chair Chem & Phys, Dom 36, Moscow 117997, Russia
来源：
CATALYSTS | 2016年 / 6卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
alkanes; alcohols; alkyl hydroperoxides; aromatics; hydrogen peroxide; mechanisms of oxidation; metal-complex catalysis; oxygen; oxygenation; peroxyacids; C-H BONDS; METAL-ORGANIC FRAMEWORKS; O-2-H2O2-VANADIUM DERIVATIVE-PYRAZINE-2-CARBOXYLIC ACID; HETEROCYCLE LIGANDS SYNTHESIS; OXYGEN REBOUND MECHANISM; SIGMA-ARYL COMPLEXES; FENTON-LIKE REACTION; SCHIFF-BASE COMPLEX; GROUP-III METALS; CYCLOHEXANE OXIDATION;
D O I：
10.3390/catal6040050
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review describes new reactions catalyzed by recently discovered types of metal complexes and catalytic systems (catalyst + co-catalyst). Works of recent years (mainly 2010-2016) devoted to the oxygenations of saturated, aromatic hydrocarbons and other carbon-hydrogen compounds are surveyed. Both soluble metal complexes and solid metal compounds catalyze such transformations. Molecular oxygen, hydrogen peroxide, alkyl peroxides, and peroxy acids were used in these reactions as oxidants.
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页数：40
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