Rhodium(iii)-catalyzed switchable C-H acylmethylation and annulation of 2,2′-bipyridine derivatives with sulfoxonium ylides

被引:5
|
作者
Chen, Mengjia [1 ]
Meng, Haifang [1 ]
Yang, Fang [1 ]
Wang, Yani [1 ]
Chen, Chen [1 ]
Zhu, Bolin [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1039/d1ob00590a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel protocol for Rh(iii)-catalyzed switchable C-H acylmethylation and annulation of 2,2 '-bipyridine derivatives with sulfoxonium ylides is reported. This protocol provides a facile approach to synthesize structurally diverse acylmethylated 2,2 '-bipyridine derivatives and acyl pyrido[2,3-a]indolizines with a broad range of functional group tolerance.
引用
收藏
页码:4268 / 4271
页数:4
相关论文
共 50 条
  • [21] Redox-Neutral Rhodium(III)-Catalyzed Annulation of Arylhydrazines with Sulfoxonium Ylides To Synthesize 2-Arylindoles
    Lv, Ningning
    Chen, Zhengkai
    Liu, Zhanxiang
    Zhang, Yuhong
    JOURNAL OF ORGANIC CHEMISTRY, 2019, 84 (20): : 13013 - 13021
  • [22] Rhodium(III)-Catalyzed Annulative Coupling of Sulfoxonium Ylides and Allenoates: An Arene C-H Activation/Cyclopropanation Cascade
    Lou, Jiang
    Wang, Quannan
    Zhou, Yong-Gui
    Yu, Zhengkun
    ORGANIC LETTERS, 2019, 21 (22) : 9217 - 9222
  • [23] Rh(III)-Catalyzed [4+2] Annulation of Indoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone Derivatives
    Shu, Sai
    Huang, Zhibin
    Chen, Yujie
    Yang, Shan
    Jiang, Yaqiqi
    Zhang, Jingyu
    Zhao, Yingsheng
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (08) : 3171 - 3179
  • [24] Ru(ii)-Catalyzed C-H bond activation/annulation of N-iminopyridinium ylides with sulfoxonium ylides
    Li, Xiang
    Li, Danlu
    Zhang, Xiaofei
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (07) : 1475 - 1479
  • [25] Rhodium-Catalyzed Tandem Acylmethylation/Annulation Reactions of 2-Aryl-2H-indazoles with Sulfoxonium Ylides: Easy Access to 6-Arylindazolo[2,3-a]quinolines
    Tang Zhen
    Pi Chao
    Wu Yangjie
    Cui Xiuling
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2023, 43 (03) : 1187 - 1196
  • [26] Rh(iii)-catalyzed redox-neutral C-H activation/annulation of oxadiazolones with sulfoxonium ylides to access oxadiazoloisoquinolinone
    Ganesh, Pothapragada S. K. Prabhakar
    Kamaraj, Eswaran
    Veeramani, Vairaperumal
    Rajamohan, Rajaram
    Perumal, Muthuraja
    New Journal of Chemistry, 2025, 49 (12) : 5093 - 5098
  • [27] Direct synthesis of benzoxazinones via Cp*Co(III)-catalyzed C-H activation and annulation of sulfoxonium ylides with dioxazolones
    Yu, Yongqi
    Xia, Zhen
    Wu, Qianlong
    Liu, Da
    Yu, Lin
    Xiao, Yuanjiu
    Tan, Ze
    Deng, Wei
    Zhu, Gangguo
    CHINESE CHEMICAL LETTERS, 2021, 32 (03) : 1263 - 1266
  • [28] Rhodium(iii)-catalysed decarboxylative C-H functionalization of isoxazoles with alkenes and sulfoxonium ylides
    Yugandar, Somaraju
    Morita, Taiki
    Nakamura, Hiroyuki
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2020, 18 (42) : 8625 - 8628
  • [29] Rhodium(III)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C-H activation
    Xu, Youwei
    Zheng, Guangfan
    Yang, Xifa
    Li, Xingwei
    CHEMICAL COMMUNICATIONS, 2018, 54 (06) : 670 - 673
  • [30] Ru(ii)-catalyzed C6-selective C-H acylmethylation of pyridones using sulfoxonium ylides as carbene precursors
    Fu, Yangjie
    Wang, Zhaohui
    Zhang, Qiyu
    Li, Zhiyu
    Liu, Hong
    Bi, Xiaoling
    Wang, Jiang
    RSC ADVANCES, 2020, 10 (11) : 6351 - 6355