Dual behaviour of acetylacetonate anions in the hydrogen-Bonded supramolecular structure (acetylacetonato-O,O′)[trans (1R,2R)-diaminocyclohexane-N,N′]-platinum(II) acetylacetonate

被引：5
|
作者：
Yuge, H [1 ]
Miyamoto, TK [1 ]
机构：
[1] Kitasato Univ, Sch Sci, Dept Chem, Kanagawa 228, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270197010792
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Pt(C5H7O2)(C6H14N2)](C5H7O2), involves two independent acetylacetonate anions with different behaviour; one is a planar chelating ligand bound to the Pt atom in the square-planar coordination sphere, and the other is a counteranion with an E formation. The latter anion links between its carbonyl O atoms and the amino groups of the cationic complexes to form the hydrogen-bonded network.
引用
收藏
页码：1816 / 1819
页数：4
相关论文
共 50 条
  • [31] Synthesis and structural studies of (1R,2R,5R)-chloro{o-[β-(2-hydroxy-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylidenamino)ethyliminomethyl]phenoxy-O,N,N}palladium(II)
    Zalevskaya, O. A.
    Vorobieva, E. G.
    Dvornikova, I. A.
    Alekseev, I. N.
    Mironova, E. V.
    Krivolapov, D. B.
    Litvinov, I. A.
    Kuchin, A. V.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (03) : 211 - 214
  • [32] Synthesis and structural studies of (1R,2R,5R)-chloro{o-[β-(2-hydroxy-2,6,6-trimethylbicyclo[3.1.1]hept-3-ylidenamino)ethyliminomethyl]phenoxy-O,N,N}palladium(II)
    O. A. Zalevskaya
    E. G. Vorobieva
    I. A. Dvornikova
    I. N. Alekseev
    E. V. Mironova
    D. B. Krivolapov
    I. A. Litvinov
    A. V. Kuchin
    Russian Journal of Coordination Chemistry, 2011, 37 : 211 - 214
  • [33] Solvent Mediated Hydrogen-bonded Supramolecular Network of a Cu(II) Complex Involving N2O Donor Ligand and Terephthalate
    Chakraborty, Jishnunil
    JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2011, 55 (02): : 199 - 203
  • [34] Hydrogen-bonded supramolecular architectures in (N-(methylpyridin-2-yl)-amidino-O-alkylurea)copper(II) halides
    Suksangpanya, U
    Blake, AJ
    Cade, EL
    Hubberstey, P
    Parker, DJ
    Wilson, C
    CRYSTENGCOMM, 2004, 6 : 159 - 167
  • [35] (SP-4-1)-bis{aqua[(1R,2R)-N,N′-bis(salicylidene)-cyclohexane-1,2-diyldiamine-κ4O,N,N′,O′]manganese(III)}-di-μ-cyano-κ4N:C-[dicyanonickel(II)]
    Akitsu, T
    Takeuchi, Y
    Einaga, Y
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : M502 - M505
  • [36] In vitro antitumor activity, intracellular accumulation, and DNA adduct formation of cis-[((1R,2R)-1,2-cyclohexanediamine-N,N′)bis(myristato)] platinum (II) suspended in lipiodol
    Kishimoto, S
    Miyazawa, K
    Fukushima, S
    Takeuchi, Y
    JAPANESE JOURNAL OF CANCER RESEARCH, 2000, 91 (01): : 99 - 104
  • [37] Cytotoxicity of cis-[((1R,2R)-1,2-cyclohexanediamine-N,N′)bis(myristato)]-platinum (II) suspended in lipiodol in a newly established cisplatin-resistant rat hepatoma cell line
    Kishimoto, S
    Miyazawa, K
    Terakawa, Y
    Ashikari, H
    Ohtani, A
    Fukushima, S
    Takeuchi, Y
    JAPANESE JOURNAL OF CANCER RESEARCH, 2000, 91 (12): : 1326 - 1332
  • [38] Crystal structure of chlorido(2,2′-((1E,1′E)-(((1R,2R)-cyclohexane-1,2-diyl)bis(azanylylidene))bis(methylylidene))diphenolato-K4N,N′,O,O′)iron(III), C20H20ClFeN2O2
    Chen, Xia
    Xue, Chongchong
    Zhang, Daopeng
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (01): : 25 - 27
  • [39] In vitro cytotoxicity of cis[((1R,2R)-1,2-cyclohexanediamine-N,N′)bis(myristato)] platinum(II) suspended in Lipiodol in rat hepatoma AH-109A cells and human tumor cell lines
    Kishimoto, S
    Noguchi, T
    Yamaoka, T
    Fukushima, S
    Takeuchi, Y
    BIOLOGICAL & PHARMACEUTICAL BULLETIN, 2000, 23 (04) : 487 - 491
  • [40] Synthesis and Crystal Structure of a Hydrogen-bonded Supramolecular Compound [（C6H5N2O）3·Cu1.5]·6H2O
    杜巧云
    辛凌云
    李云平
    曹佃省
    Chinese Journal of Structural Chemistry, 2006, (03) : 295 - 299
12345