Dual behaviour of acetylacetonate anions in the hydrogen-Bonded supramolecular structure (acetylacetonato-O,O′)[trans (1R,2R)-diaminocyclohexane-N,N′]-platinum(II) acetylacetonate

被引：5
|
作者：
Yuge, H [1 ]
Miyamoto, TK [1 ]
机构：
[1] Kitasato Univ, Sch Sci, Dept Chem, Kanagawa 228, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270197010792
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Pt(C5H7O2)(C6H14N2)](C5H7O2), involves two independent acetylacetonate anions with different behaviour; one is a planar chelating ligand bound to the Pt atom in the square-planar coordination sphere, and the other is a counteranion with an E formation. The latter anion links between its carbonyl O atoms and the amino groups of the cationic complexes to form the hydrogen-bonded network.
引用
收藏
页码：1816 / 1819
页数：4
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