Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission

被引：25
|
作者：
Wang, Zhen [1 ]
Yan, Sen [1 ]
Cui, Huang-Chen [1 ]
Cheng, Guang [2 ]
Ma, Hui [1 ]
Zhang, Qing-Mei [1 ]
Zhang, Qing-Pu [1 ]
Liu, Jun-Min [3 ]
Tan, Bien [2 ]
Zhang, Chun [1 ]
机构：
[1] Huazhong Univ Sci & Technol, Coll Life Sci & Technol, Natl Engn Res Ctr Nanomed, Wuhan 430074, Hubei, Peoples R China
[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China
[3] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
来源：
MACROMOLECULES | 2018年 / 51卷 / 19期
基金：
中国国家自然科学基金;
关键词：
CONJUGATED MICROPOROUS POLYMERS; GAS-STORAGE; SURFACE-AREA; SOLID-STATE; FRAMEWORKS; TETRAPHENYLETHYLENE; NANOPARTICLES; CONFORMATION; RECOGNITION; NETWORKS;
D O I：
10.1021/acs.macromol.8b01632
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A tetraphenylethylene-based oxacalixarene macrocycle (TOM) with high fluorescence quantum yield (70%) was used as monomer to construct a fluorescent macrocycle-based porous organic polymer (pTOM). With high surface area, specific pore size, and emissive properties, the blue-greenish fluorescent pTOM can be developed into white-light-emission materials by adsorbing guests of tris(bipyridine)ruthenium with complementary emission color by the Forster resonance energy transfer (FRET) effect.
引用
收藏
页码：7863 / 7871
页数：9
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