Porous Organic Polymer from Aggregation-Induced Emission Macrocycle for White-Light Emission

被引：25

作者：

Wang, Zhen ^{[1
]}

Yan, Sen ^{[1
]}

Cui, Huang-Chen ^{[1
]}

Cheng, Guang ^{[2
]}

Ma, Hui ^{[1
]}

Zhang, Qing-Mei ^{[1
]}

Zhang, Qing-Pu ^{[1
]}

Liu, Jun-Min ^{[3
]}

Tan, Bien ^{[2
]}

Zhang, Chun ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Coll Life Sci & Technol, Natl Engn Res Ctr Nanomed, Wuhan 430074, Hubei, Peoples R China

[2] Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Hubei, Peoples R China

[3] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

MACROMOLECULES | 2018年 / 51卷 / 19期

基金：

中国国家自然科学基金;

关键词：

CONJUGATED MICROPOROUS POLYMERS; GAS-STORAGE; SURFACE-AREA; SOLID-STATE; FRAMEWORKS; TETRAPHENYLETHYLENE; NANOPARTICLES; CONFORMATION; RECOGNITION; NETWORKS;

D O I：

10.1021/acs.macromol.8b01632

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A tetraphenylethylene-based oxacalixarene macrocycle (TOM) with high fluorescence quantum yield (70%) was used as monomer to construct a fluorescent macrocycle-based porous organic polymer (pTOM). With high surface area, specific pore size, and emissive properties, the blue-greenish fluorescent pTOM can be developed into white-light-emission materials by adsorbing guests of tris(bipyridine)ruthenium with complementary emission color by the Forster resonance energy transfer (FRET) effect.

引用

页码：7863 / 7871

页数：9

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