New polyaza macrobicyclic cryptands based on 1,2,4-triazole ligands and their Cu(I), Ag(I), Cu(II) and Ni(II) complexes

被引:10
|
作者
Cabezón, B [1 ]
Irurzun, M [1 ]
Torres, T [1 ]
Vázquez, P [1 ]
机构
[1] Univ Autonoma Madrid, Dept Quim Organ CI, E-28049 Madrid, Spain
关键词
D O I
10.1016/S0040-4039(97)10729-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
New polytopic cryptands 2-4 containing 1,2,4-triazole subunits have been synthesized by [2+3] condensation of the corresponding acyltriazole 5 and tris(2-aminoethyl)amine (Tren) in excellent yield; 2 and 3 gave dinuclear Ag(I) and trinuclear Cu(I) cryptates, and 4 yielded trinuclear NI(II) and Cu(II) complexes in alkaline media. The nature of the complexes has been established by LSIMS and MALDI-TOF mass spectrometry. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1067 / 1070
页数:4
相关论文
共 50 条
  • [21] PREPARATION AND SPECTRAL CHARACTERIZATION OF COMPLEXES OF 4-AMINO-3-HYDRAZINO-1,2,4-TRIAZOLE HYDROCHLORIDE WITH CO(II), NI(II) AND CU(II)
    GARG, BS
    SINGH, PK
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1990, 20 (02): : 209 - 222
  • [22] Synthesis, spectral characterization, in vitro antibacterial, antifungal and cytotoxic activities of Co(II), Ni(II) and Cu(II) complexes with 1,2,4-triazole Schiff bases
    Bagihalli, Gangadhar B.
    Avaji, Prakash Gouda
    Patil, Sangamesh A.
    Badami, Prema S.
    [J]. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2008, 43 (12) : 2639 - 2649
  • [23] Binuclear complexes of palladium(II) with 1,2,4-triazole
    Grap, SR
    Kurbakova, AP
    Efimenko, IA
    [J]. ZHURNAL NEORGANICHESKOI KHIMII, 1995, 40 (02): : 250 - 253
  • [24] Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)-A Review
    Aly, Ashraf A.
    Abdallah, Elham M.
    Ahmed, Salwa A.
    Rabee, Mai M.
    Braese, Stefan
    [J]. MOLECULES, 2023, 28 (04):
  • [25] COMPLEXES OF 2-MERCAPTOBENZOTHIAZOLE WITH CU(II), NI(II), CO(II), CD(II), ZN(II), PB(II), AG(I), AND TI(I)
    KHULLAR, IP
    AGARWALA, U
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (08): : 1165 - 1171
  • [26] 1,2,4-TRIAZOLE COMPLEXES .15. THE STRUCTURE OF TETRAAQUASULPHATO(1,2,4-TRIAZOLE)MANGANESE(II)
    GORTER, S
    ENGELFRIET, DW
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1981, 37 (JUN): : 1214 - 1218
  • [27] COMPLEXES OF CO(II), NI(II), CU(II), ZN(II) CD(II) AND AG(I) NITRATES WITH NICOTINIC-ACID AND RELATED LIGANDS
    AHUJA, IS
    SRIRAMULU, R
    SINGH, R
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1980, 19 (09): : 909 - 912
  • [28] Synthesis, spectral, thermal, magnetic and biological characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with a Schiff base bearing a 1,2,4-triazole pharmacophore
    Larisa Calu
    Mihaela Badea
    Mariana Carmen Chifiriuc
    Coralia Bleotu
    Gabriela-Iulia David
    Gabriela Ioniţă
    Luminiţa Măruţescu
    Veronica Lazăr
    Nicolae Stanică
    Irina Soponaru
    Dana Marinescu
    Rodica Olar
    [J]. Journal of Thermal Analysis and Calorimetry, 2015, 120 : 375 - 386
  • [29] Synthesis, spectral characterization, in vitro biological and DNA cleavage studies of Co(II), Ni(II), Cu(II), and Zn(II) complexes with 1,2,4-triazole Schiff bases
    Bagihalli, Gangadhar B.
    Patil, Sangamesh A.
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (10) : 1690 - 1700
  • [30] Synthesis, spectral, thermal, magnetic and biological characterization of Co(II), Ni(II), Cu(II) and Zn(II) complexes with a Schiff base bearing a 1,2,4-triazole pharmacophore
    Calu, Larisa
    Badea, Mihaela
    Chifiriuc, Mariana Carmen
    Bleotu, Coralia
    David, Gabriela-Iulia
    Ionita, Gabriela
    Marutescu, Luminita
    Lazar, Veronica
    Stanica, Nicolae
    Soponaru, Irina
    Marinescu, Dana
    Olar, Rodica
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2015, 120 (01) : 375 - 386