Extended corresponding-states behavior for particles with variable range attractions

被引:408
|
作者
Noro, MG [1 ]
Frenkel, D [1 ]
机构
[1] FOM, Inst Atom & Mol Phys, NL-1098 SJ Amsterdam, Netherlands
来源
JOURNAL OF CHEMICAL PHYSICS | 2000年 / 113卷 / 08期
关键词
D O I
10.1063/1.1288684
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose an extension of the law of corresponding states that can be applied to systems-such as colloidal suspensions-that have widely different ranges of attractive interactions. We argue that the "reduced" second virial coefficient is a convenient parameter to quantify the effective range of attraction. Knowledge of the pair-potential alone allows one to estimate the relative location of the liquid-vapor and solid-fluid coexistence curves. (C) 2000 American Institute of Physics. [S0021-9606(00)52432-5].
引用
收藏
页码:2941 / 2944
页数:4
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