Solubility of d-element salts in organic and aqueous-organic solvents: II. Effect of halocomplex formation on solubility of cobalt bromide and chloride and nickel chloride

被引：12
|
作者：
Gorbunov, A. O. [1 ]
Tsyrul'nikov, N. A. [1 ,2 ]
Tikhomirova, A. A. [1 ,2 ]
Bogachev, N. A. [1 ]
Skripkin, M. Yu. [1 ]
Nikolskii, A. B. [1 ]
Pestova, O. N. [1 ]
机构：
[1] St Petersburg State Univ, Univ Skaya Nab 7-9, St Petersburg 199034, Russia
[2] Bowling Green State Univ, Ctr Photochem Sci, Dept Chem, Bowling Green, OH 43403 USA
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
solubility; ternary systems; aqueous-organic solvents; halocomplex formation; cobalt halide complexes; nickel halide complexes; SOLVATION; COMPLEXES; WATER; IONS; N; N-DIMETHYLFORMAMIDE; N-DIMETHYLACETAMIDE; DIMETHYLSULFOXIDE; MANGANESE(II); SOFTNESS;
D O I：
10.1134/S1070363216040022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solubility of salts in the systems MCl2-H2O-Solv (M = Co, Ni) and CoBr2-H2O-Solv (Solv = dimethyl sulfoxide, dimethyl formamide, and dimethyl acetamide) at 25A degrees C was measured experimentally. Dominating species of cobalt and nickel halides existing in various concentration regions were identified by analysis of electron absorption spectra. It was shown that the major factor defining solubility is the interaction of halocomplexes of metal ions with solvent molecules.
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页码：771 / 777
页数：7
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