An ytterbium(II) complex with dimethyl ester of oxydiacetic acid

被引：1
|
作者：
Starynowicz, Przemyslaw [1 ]
机构：
[1] Univ Wroclaw, PL-50383 Wroclaw, Poland
来源：
DALTON TRANSACTIONS | 2007年 / 26期
关键词：
D O I：
10.1039/b702971c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An Yb( II) complex with dimethyl ester of oxydiacetic acid, [Yb(CH3OOCCH2OCH2COOCH3)(3)]-( ClO4)(2), has been obtained by electrochemical reduction and its crystal structure has been determined. The complex cations have the D-3 (32) crystallographic symmetry. The compound shows a very broad absorption band, starting from 500 nm towards the UV region, and traces of luminescence with a maximum at 545 nm. The performed density functional theory ( DFT) calculations have shown that the absorption band results from mixed f-d and charge transfer transitions, and the empty antibonding pi* orbitals of the ester groups quench the luminescence.
引用
收藏
页码：2779 / 2783
页数：5
相关论文
共 50 条
  • [21] COORDINATION PECULIARITIES OF THE DIMETHYL ETHER OF SEMICARBAZIDEDIACETIC ACID IN ITS COPPER(II) COMPLEX
    MALINOVSKII, TI
    BOLOGA, OA
    KRAVTSOV, VK
    VEREZHAN, AV
    SIMONOV, YA
    GERBELEU, NV
    DOKLADY AKADEMII NAUK SSSR, 1991, 317 (04): : 888 - 892
  • [22] Polymeric ytterbium(II) complex with pyridyl amido ligands
    Pan, Cheng-Ling
    Hou, Chang-Min
    Zhang, Lei
    Fan, Yong
    Sheng, Shao-Ding
    MENDELEEV COMMUNICATIONS, 2012, 22 (02) : 109 - 110
  • [23] Coordination between lead and oxydiacetic acid
    Svensson, G
    Olson, S
    Albertsson, J
    ACTA CHEMICA SCANDINAVICA, 1998, 52 (07): : 868 - 872
  • [24] SYNTHESIS, STRUCTURE, AND STABILITY OF THE ZINC COMPLEX OF THE DIMETHYL ESTER OF MESO-2,3-DIMERCAPTOSUCCINIC ACID
    RIVERA, M
    FERNANDO, Q
    CHEMICAL RESEARCH IN TOXICOLOGY, 1992, 5 (01) : 142 - 147
  • [25] SYNTHESIS OF THIOANALOGS OF A CINNABARIC ACID AND ITS DIMETHYL ESTER
    NEKHOROSHEV, AA
    SEVBO, DP
    GINZBURG, OF
    ZHURNAL ORGANICHESKOI KHIMII, 1987, 23 (03): : 647 - 655
  • [26] ACETYLENEDICARBOXYLIC ACID DIMETHYL ESTER, A NEW INHIBITOR OF PHOSPHORYLATION
    TRASCH, H
    BAUERLEIN, E
    HOPPE-SEYLERS ZEITSCHRIFT FUR PHYSIOLOGISCHE CHEMIE, 1980, 361 (03): : 340 - 341
  • [27] INSULINOTROPIC ACTION OF GLUTAMIC-ACID DIMETHYL ESTER
    MALAISSE, WJ
    CONGET, I
    RASSCHAERT, J
    LECLERCQMEYER, V
    VICENT, D
    VILLANUEVAPENACARRILO, ML
    VALVERDE, I
    SENER, A
    DIABETES, 1994, 43 : A244 - A244
  • [28] INSULINOTROPIC ACTION OF GLUTAMIC-ACID DIMETHYL ESTER
    SENER, A
    CONGET, I
    RASSCHAERT, J
    LECLERCQMEYER, V
    VILLANUEVAPENACARRILLO, ML
    VALVERDE, I
    MALAISSE, WJ
    AMERICAN JOURNAL OF PHYSIOLOGY-ENDOCRINOLOGY AND METABOLISM, 1994, 267 (04): : E573 - E584
  • [29] CRYSTAL AND MOLECULAR-STRUCTURE OF THE PRODUCT OF ADDITION OF DIMETHYL ESTER OF SEMICARBAZIDEACETIC ACID TO COPPER(II) CHLORIDE
    KRAVTSOV, VK
    VEREZHAN, AV
    GERBELEU, NV
    BOLOGA, OA
    SIMONOV, YA
    MALINOWSKY, TI
    KRISTALLOGRAFIYA, 1992, 37 (01): : 122 - 128
  • [30] ORGANOBORON COMPOUNDS - HYDROBORATION OF DIMETHYL ESTER OF ALLYLBORIC ACID
    MIKHAILO.EM
    KISELEV, VG
    POZDNEV, VF
    DOKLADY AKADEMII NAUK SSSR, 1963, 151 (03): : 577 - &
12345