Bimolecular fluorescence quenching reactions of the biologically active coumarin composite 2-acetyl-3H-benzo[f]chromen-3-one in different solvents

被引：17
|
作者：
Koppal, V. V. [1 ]
Melavanki, R. M. [2 ]
Kusanur, R. A. [3 ]
Patil, N. R. [1 ]
机构：
[1] BVB Coll Engn & Technol, Dept Phys, Hubli 580031, Karnataka, India
[2] MS Ramaiah Inst Technol, Dept Phys, Bangalore, Karnataka, India
[3] RV Coll Engn, Dept Chem, Bangalore, Karnataka, India
来源：
LUMINESCENCE | 2018年 / 33卷 / 06期
关键词：
diffusion-limited reaction; fluorescence quenching; high polarity solvents; quenching models; Stern-Volmer relationship; DIFFUSION-CONTROLLED REACTIONS; STERN-VOLMER PLOTS; CARBON-TETRACHLORIDE; ANTIMICROBIAL ACTIVITY; ANILINE; MIXTURES; INDOLE; TEMPERATURE; DERIVATIVES; TRANSIENT;
D O I：
10.1002/bio.3502
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A study on fluorescence quenching was carried out for the coumarin derivative 2-acetyl-3H-benzo[f]chromen-3-one (2AHBC) with aniline at room temperature. Efficient fluorescence quenching was observed and Stern-Volmer (S-V) plots showed upward curves from linearity in all solvents of different polarities. For the solute 2AHBC, ground state complex formation does not hold in our study. The kinetic distance (r) value was found to be greater than the encounter distance (R) and indicated that the quenching reaction was held within the sphere of action. Diffusion-limited reactions were found to be more prominent in high polarity solvents, namely dimethyl sulfoxide (DMSO), DMF, ACN, methanol, ethanol, propanol and DCM. The relationships between quenching constant (K-SV) and dielectric constants (epsilon) of the different solvents were studied.
引用
收藏
页码：1019 / 1025
页数：7
相关论文
共 50 条
  • [21] Synthesis Antimicrobial Activities and Side Reactions of 4-Methyl-3-acetyl-2-heterocyclic-2H,3H-benzo[f]-1,5-thiazepines
    Wu, Yunyun
    Tian, Keqing
    Yang, Tian
    Du, Xingqiong
    Zhang, Ping
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2013, 33 (07) : 1465 - 1471
  • [22] Reactions of zinc enolates derived from 1-aryl-2,2-di-bromoalkanones with 2-acyl-3H-benzo[f]chromen-3-ones, 6-bromo-2-oxochromene-3-carboxamides, and 3-oxo-3H-benzo[f]chromene-2-carboxamides
    Shchepin, VV
    Kalyuzhnyi, MM
    Silaichev, PS
    Russkikh, NY
    Shchepin, RV
    Ezhikova, MA
    Kodess, MI
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 40 (09) : 1353 - 1358
  • [23] Reactions of zinc enolates derived from 1-aryl-2,2-di-bromoalkanones with 2-acyl-3H-benzo[f]chromen-3-ones, 6-bromo-2-oxochromene-3-carboxamides, and 3-oxo-3H-benzo-[f]chromene-2-carboxamides
    V. V. Shchepin
    M. M. Kalyuzhnyi
    P. S. Silaichev
    N. Yu. Russkikh
    R. V. Shchepin
    M. A. Ezhikova
    M. I. Kodess
    Russian Journal of Organic Chemistry, 2004, 40 : 1353 - 1358
  • [24] Reactions of zinc enolates derived from 1-aryl-2-bromoalkanones and 1-aryl-2-bromo-2-phenylethanone with 3-aroyl-6-bromochromen-2-ones and 2-benzoylbenzo[f]chromen-3-one
    Shchepin, V. V.
    Korzun, A. E.
    Valkhrin, M. I.
    Silaichev, P. S.
    Ezhikova, M. A.
    Kodess, M. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (09) : 1344 - 1347
  • [25] Synthesis, Spectroscopic (FT-IR, FT-Raman), Electronic Properties and Molecular Docking Studies of 1-(2, 6-dibromo-4-methyl-phenoxymethyl)-benzo[f]chromen-3-one
    Hiremath, Sudhir M.
    Khemalapure, Seema S.
    CHEMISTRYSELECT, 2023, 8 (25):
  • [26] Reactions of zinc enolates derived from 1-aryl-2-bromo-alkanones and 1-aryl-2-bromo-2-phenylethanone with 3-aroyl-6-bromochromen-2-ones and 2-benzoylbenzo[f]chromen-3-one
    V. V. Shchepin
    A. E. Korzun
    M. I. Vakhrin
    P. S. Silaichev
    M. A. Ezhikova
    M. I. Kodess
    Russian Journal of Organic Chemistry, 2006, 42 : 1344 - 1347
  • [27] Crystal structure of 3-[4-(benzyloxy)phenyl]-2,3-dihydro-1H-benzo[f]chromen-1-one
    Vasanthi, R.
    Jonathan, D. Reuben
    Ezhilarasi, K. S.
    Sathya, S.
    Usha, G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1116 - +
  • [28] Effect of temperature and quencher on the fluorescence of 4-(5-methyl-3-furan-2-yl-benzofuran-2-yl)-7-methyl-chromen-2-one in different solvents
    Evale, Basavaraj G.
    Hanagodimath, S. M.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2010, 75 (05) : 1592 - 1599
  • [29] ESIPT-induced intersystem crossing leads to tautomer fluorescence quenching for 3-mercapto-2-(4-(trifluoromethyl)phenyl)-4H-chromen-4-one molecule
    Jiang, Meng-Huan
    Li, Mai-Ning
    Zhao, Yu
    Liu, Yu-Hui
    Gao, Jun
    Zhu, Chaoyuan
    Journal of Photochemistry and Photobiology A: Chemistry, 2025, 459
  • [30] Studies on Fluorescence Quenching, Decay Rate Parameters, Dipole Moment, Rotational Diffusion of 3-(benzo[d]thiazol-2-yl)-7-(diethylamino)-2H-chromen-2-one Laser Dye in Excited Singlet State: Temperature Effect
    Kumar, Anil
    Basappa, M.
    Renuka, C. G.
    JOURNAL OF FLUORESCENCE, 2024,
12345