Aggregation-induced emission in precursors to porous molecular crystals

被引:17
|
作者
Zhang, Zhenglin [1 ]
Hashim, Mohamed I. [1 ]
Miljanic, Ognjen S. [1 ]
机构
[1] Univ Houston, Dept Chem, 112 Fleming Bldg, Houston, TX 77204 USA
基金
美国国家科学基金会;
关键词
INTRAMOLECULAR CHARGE-TRANSFER; SOLID-STATE; LIGHT-EMISSION; MECHANISM; PHOTOLUMINESCENCE; FLUORESCENCE; ENHANCEMENT; RESTRICTION; ADSORPTION;
D O I
10.1039/c7cc03814c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trigonal fluorinated pyrazoles assemble into porous molecular crystals and show solid-state fluorescence. However, in a DMF/H2O mixed solvent system, the triazine-centered compound displays aggregation-induced emission, while its benzene-based counterpart does not.
引用
收藏
页码:10022 / 10025
页数:4
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