Intramolecular CO a⟨- H interaction in Arene(tricarbonyl)-chromium complexes

被引：4
|
作者：
Bodrikov, I. V. [1 ]
Grinval'd, I. I. [1 ]
Artemov, A. N. [1 ]
Bazhan, L. I. [1 ]
Kalagaev, I. Yu. [1 ]
机构：
[1] Alekseev Nizhnii Novgorod State Tech Univ, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 01期
关键词：
General Chemistry; Lone Electron Pair; Diethylene Glycol; Tricarbonyl; Chromium Complex;
D O I：
10.1134/S1070363210010032
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unlike benzene(tricarbonyl)chromium which displays two carbonyl stretching vibrations bands in the IR spectrum, analogous tricarbonylchromium complexes of the general formula (C(6)H(5)ZMe)Cr(CO)(3) [Z = O, CH(OH), N(Pr), CH=CH] are characterized by three carbonyl bands, one of which is displaced to the low-frequency region. The appearance of that band was rationalized in terms of intramolecular interaction between hydrogen atoms in the substituent on the benzene ring and carbonyl groups.
引用
收藏
页码：20 / 22
页数：3
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