Thermodynamics and hydrodynamics (statistical foundations): 2. Thermodynamic equilibrium

被引:4
|
作者
Martynov, GA [1 ]
机构
[1] RAS, Inst Phys Chem, Moscow 117901, Russia
关键词
equilibrium BBGKY hierarchy; local approach; Gibbs distribution; Ornstein-Zernike equation; correlation sphere; thermostat;
D O I
10.1023/A:1022288306763
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We show that the BBGKY hierarchy in thermodynamic equilibrium degenerates into an equilibrium hierarchy. In turn, the latter can be used to obtain both the fundamental system of equations describing the state of matter inside a correlation sphere of the radius R approximate to 10(-7) cm and the canonical Gibbs distribution, which, according to the current concepts, describes the state of the entire macroscopic system. We show that the Gibbs distribution is indeed also local, i.e., describes the state of matter only inside the correlation sphere, in the thermostat surrounding this sphere, the Gibbs distribution degenerates into a constant. We state that these two approaches are equivalent to each other.
引用
收藏
页码:285 / 294
页数:10
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