Novel Anthracene-Based Cylindrical Macrotricyclic Polyether: Powerful Host for Bispyridinium Dications

被引：26

作者：

Su, Yong-Sheng ^{[1
,2
]}

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 08期

基金：

中国国家自然科学基金;

关键词：

PARAQUAT DERIVATIVES; CYCLIC POLYETHERS; CROWN-ETHERS; METAL-SALTS; COMPLEXATION; CONSTANTS; CRYPTANDS; AMMONIUM; SYSTEMS;

D O I：

10.1021/ol100589u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel anthracene-based cylindrical macrotricyclic polyether containing two dibenzo-30-crown-10 cavities has been synthesized and shown to be a powerful host to form 1:1 stable complexes with the rodlike bispyridinium dications (K(a) > 105 M(-1)). Moreover, it was found that the complexes could all self-assemble into linear supramolecular arrays and further 2D mosaic-like architectures in the solid state.

引用

页码：1888 / 1891

页数：4

共 43 条

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