CRYSTAL STRUCTURE OF COORDINATION POLYMERS BASED ON A HETEROMETALLIC CARBOXYLATE COMPLEX

被引：11

作者：

Sapianik, A. A. ^{[1
,2
]}

Semenenko, E. E. ^{[2
]}

Samsonenko, D. G. ^{[1
,2
]}

Dybtsev, D. N. ^{[1
,2
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 02期

关键词：

lithium; zinc; coordination polymers; metal-organic frameworks; polynuclear complexes; carboxylate complexes; single crystal X-ray diffraction analysis; METAL-ORGANIC FRAMEWORKS;

D O I：

10.1134/S0022476618020336

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new metal-organic frameworks [Zn(Hibdc)(2)]center dot DMF (1), (H2NMe (2))[Li2Zn3(H2O)(dmf)(Hbtc)(3)(btc)]center dot 6DMF center dot H2O(2), and [Li2Zn2(H2O)(2) (bpp)(bpdc)(3)]center dot 7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)(6)(py)(2)] with isophthalic (H(2)ibdc) and trimesic (H(3)btc) acids and in the presence of both 4,4'-biphenyldicarboxylic acid (H(2)bpdc) and 4,4'-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.

引用

页码：487 / 493

页数：7

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