Nanocomposite multilayer films containing Dawson-type polyoxometalate and cationic phthalocyanine: Fabrication, characterization and bifunctional electrocatalytic properties

被引：22

作者：

Jin, Yana ^{[1
]}

Xu, Lin ^{[1
]}

Zhu, Liande ^{[1
]}

An, Wenjia ^{[1
]}

Gao, Guanggang ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxomet Sci, Changchun 130024, Peoples R China

来源：

THIN SOLID FILMS | 2007年 / 515卷 / 13期

基金：

中国国家自然科学基金;

关键词：

multilayer films; polyoxometalate; alcian blue; bifunctional electrocatalysis;

D O I：

10.1016/j.tsf.2006.12.175

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Water-soluble cationic phthalocyanine - Alcian blue (AB) and 2:18 tungstophosphate anions (P2W18) were alternately deposited on a -aminopropyltriethoxysilane-modified indium tin oxide-coated glass electrodes or quartz substrate through a layer-by-layer method. The resulting organic-inorganic hybrid films were characterized by ultraviolet-visible absorption spectra, cyclic voltammetry and X-ray photoelectron spectra. A stepwise and regular deposition of AB and P2W18 in both pure water and 0.01 M poly(styrenesulfonate) (PSS) were investigated. Differences in linear growth were observed between pure water and 0.01 M PSS-based solutions. The voltammetric curves show well-defined anodic and cathodic peaks, which is indicative of both electrocatalytic oxidation and reduction of nitrite. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：5490 / 5497

页数：8