Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl] (methyl)aminol} ethoxy-substituted metallophthalocyanines

被引：2
|
作者：
Zengin, Hilal [1 ]
Yenilmez, Hacer Yasemin [1 ]
Burat, Ayfer Kalkan [1 ]
Bayir, Zehra Altuntas [1 ]
机构：
[1] Istanbul Tech Univ, Dept Chem, Fac Sci & Letters, TR-80626 Istanbul, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 06期
关键词：
Phthalocyanine; 2-{[2(dimethylamino)ethyl]-methylamino} ethanol; water-soluble; UNSYMMETRICAL PHTHALOCYANINES; PHOTOPHYSICAL PROPERTIES; METAL-FREE; COMPLEXES;
D O I：
10.3906/kim-1405-26
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2{[2-(dimethylamino)ethyl](methyl)aminof ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, H-1 NMR, FT-IR, and UV-Vis spectral data.
引用
收藏
页码：1094 / 1101
页数：8
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