Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl] (methyl)aminol} ethoxy-substituted metallophthalocyanines

被引：2

作者：

Zengin, Hilal ^{[1
]}

Yenilmez, Hacer Yasemin ^{[1
]}

Burat, Ayfer Kalkan ^{[1
]}

Bayir, Zehra Altuntas ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem, Fac Sci & Letters, TR-80626 Istanbul, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 06期

关键词：

Phthalocyanine; 2-{[2(dimethylamino)ethyl]-methylamino} ethanol; water-soluble; UNSYMMETRICAL PHTHALOCYANINES; PHOTOPHYSICAL PROPERTIES; METAL-FREE; COMPLEXES;

D O I：

10.3906/kim-1405-26

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2{[2-(dimethylamino)ethyl](methyl)aminof ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, H-1 NMR, FT-IR, and UV-Vis spectral data.

引用

页码：1094 / 1101

页数：8

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