Anionic effects on Raman OD stretching spectra for alcoholic LiX solutions (X = Cl-, Br-, I-, ClO4-, NO3-, and CH3COO-)

被引：16

作者：

Hidaka, F ^{[1
]}

Yoshimura, Y ^{[1
]}

Kanno, H ^{[1
]}

机构：

[1] Natl Def Acad, Dept Appl Chem, Kanagawa 2398686, Japan

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2003年 / 32卷 / 03期

关键词：

alcoholic lithium salt solutions; anionic effect; Raman spectra; OD stretching vibration; glassy state;

D O I：

10.1023/A:1022986301621

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman OD stretching spectra of alcoholic LiX (X = Cl-, Br-, I-, ClO4-, NO3-, and CH3COO-) solutions ( alcohols D methanol and ethanol) were measured in the liquid state at room temperature and in the glassy state at liquid nitrogen temperature. The effects of the anions on the Raman OD stretching spectra in these alcoholic solutions are investigated and the structural changes of the solutions are discussed. It is shown that the structure-breaking effects of anions on the intrinsic alcoholic structure increase in the order: Cl- < Br- < I- < ClO4-. From spectral changes, it seems that CH3COOLi exerts little effect on the liquid structure of the alcohol.

引用

页码：239 / 251

页数：13

共 50 条

[31] Influence of the anion base X (X=F-, Cl-, Br-, NO3- and SO42-) on the formation of Chalcogen bonds in Chalcogenodiazoles C4N4Ch (Ch=S, Se and Te)
Li, Bin
Wang, Xiaoting
Wang, Hui
Song, Qi
Ni, Yuxiang
Wang, Hongyan
Wang, Xudong
JOURNAL OF MOLECULAR STRUCTURE, 2022, 1265
[32] ANION-EXCHANGE SELECTIVITY OF CLO4-, CNS-, I- AND NO3- ON DOWEX L-X8 (CL) IN WATER-2-METHOXYETHANOL MIXED-MEDIA
PATIL, BH
MATH, BV
NARKE, CS
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1992, 69 (03) : 136 - 137
[33] Hexarhenium(III) clusters [Re6(μ3-S)8X6]4- (X- = Cl-, Br-, I-) are luminescent at room temperature
Yoshimura, T
Ishizaka, S
Umakoshi, K
Sasaki, Y
Kim, HB
Kitamura, N
CHEMISTRY LETTERS, 1999, (07) : 697 - 698
[34] Colloidal nanocrystals of APbX3 [A= Cs+, CH3NH3+, CH(NH2) 2+, X= Cl-, Br-, I-] perovskites with bright photoluminescence spanning the entire visible spectral range
Kovalenko, Maksym
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[35] EFFECT OF LATTICE ANIONS ON THE RACEMIZATION OF OPTICALLY-ACTIVE METAL CHELATE SALTS IN THE SOLID-STATE .1. [FE(PHEN)3]X2,[FE(BPY)3]X2,[NI(PHEN)3]X2, AND [NI(BPY)3]X2, WHERE X-=CL-,BR-,I-, OR CLO4-
FUJIWARA, T
YAMAMOTO, Y
INORGANIC CHEMISTRY, 1980, 19 (07) : 1903 - 1907
[36] Synthesis and large crystal growth of a family of mixed-anionic methanesulfonate salts by anionic site-substitution: Na5(SO3CH3)4(X) (X = BF4-, ClO4-, PF6-, I-)
Gabilondo, Eric A.
Halasyamani, P. Shiv
DALTON TRANSACTIONS, 2025, 54 (13) : 5301 - 5310
[37] Theoretical study of (FH2X)n•Y (X = P and As, n=1-4, Y = F-, Cl-, Br-, I-, NO3- and SO42-): The possibility of anion recognition based on pnicogen bonding
Chen, YiShan
Yao, LiFeng
Lin, XueFei
COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2014, 1036 : 44 - 50
[38] SYNTHESIS AND THERMAL INVESTIGATIONS OF RUTHENIUM(II) PHENANTHROLINE COMPLEXES OF [RU(PHEN)3]X2 TYPE, WHERE X = CL-, BR-, I-, SCN-, VO3-, REO4-
BUJEWSKI, A
WALEWSKI, M
GRZEDZICKI, K
DOBROWOLSKI, J
THERMOCHIMICA ACTA, 1990, 159 : 247 - 254
[39] Syntheses and characterization of lead(II) complexes, Pb(dmphen)X2 (X = NO3-, CLO4- and CH3COO-;: Dmphen=2,9-dimethyl-1,10-phenanthroline), and crystal structure of [Pb(dmphen)(NO3)2]n, a new polymeric compound with holodirected geometry
Morsali, A
Mahjoub, AR
Hosseinian, A
JOURNAL OF COORDINATION CHEMISTRY, 2004, 57 (08) : 685 - 692
[40] 碳酸酐酶活性部位模型化合物{η3-HB（3-Phpz）3ZnX}（X=Cl-,Br-,I-,NO3-）的合成、表征及量子化学研究
杨科武
王永珍
黄仲贤
殷元骐
化学学报, 1997, (03) : 209 - 214

← 1 2 3 4 5 →