Ruthenium-catalysed cleavage of alkenes and alkynes to carboxylic acids

被引:41
|
作者
Griffith, WP [1 ]
Shoair, AG [1 ]
Suriaatmaja, M [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
关键词
D O I
10.1080/00397910008086915
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Catalysis of alkene and alkyne cleavage to carboxylic acids by ruthenium trichloride in the presence of an excess of periodic acid has been studied in biphasic H2O - CC4-CH3CN media, and is found to be simple and effective. The active catalyst is shown to be RuO4.
引用
收藏
页码:3091 / 3095
页数:5
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