A new preparation of esters from carbonyl compounds following lithium aluminum hydride reduction

被引：1
|
作者：
Guo, ZM
Sindelar, RD [1 ]
机构：
[1] Univ Mississippi, Sch Pharm, Pharmaceut Sci Res Inst, Dept Med Chem, University, MS 38677 USA
[2] Univ Mississippi, Sch Pharm, Pharmaceut Sci Res Inst, Natl Ctr Dev Nat Prod, University, MS 38677 USA
来源：
SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 06期
关键词：
D O I：
10.1080/00397919808003071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A modified work-up procedure for the Lithium aluminum hydride (LiAlH4) reduction of esters and other carbonyl compounds is described. The one pot procedure converts an ester to its "homo-reverse ester" and other carbonyl compounds to esters. The key step is trapping the resulting intermediate aluminum alkoxide during reflux with an ester.
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页码：1031 / 1039
页数：9
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