Difficult reptation of star-shaped polystyrenes in their blends with poly(methyl methacrylate)

被引:0
|
作者
Dondos, A [1 ]
Christopoulou, V
Papanagopoulos, D
机构
[1] Univ Patras, Dept Chem Engn, Patras 26500, Greece
[2] Inst Chem Engn & High Temp Proc, Patras 26500, Greece
关键词
D O I
10.1002/1521-3927(20001001)21:15<1086::AID-MARC1086>3.0.CO;2-Q
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Films of polystyrene/poly(methyl methacrylate) (PS/PMMA) blends are obtained from solution after evaporation of the solvent. The degree of mixing of the two polymers is studied using scanning electron microscopy after selective elimination of the PS phase. Using star-shaped instead of linear PS, an important degree of mixing is observed. This must be attributed to difficult reptation of the star-shaped chains due to the high number of entanglements between star-shaped PS and PMMA compared to the entanglements between learn PS and PMMA.
引用
收藏
页码:1086 / 1088
页数:3
相关论文
共 50 条
  • [21] Synthesis of star-shaped polystyrenes with glucose in the chain-end and core
    Kaga, H
    Yamane, S
    Narumi, A
    Satoh, T
    Kakuchi, T
    MACROMOLECULAR SYMPOSIA, 2004, 217 : 29 - 38
  • [22] Separation of linear and star-shaped polystyrenes by two-dimensional chromatography
    Gerber, J
    Radke, W
    E-POLYMERS, 2005,
  • [23] TEMPERATURE-DEPENDENCE OF THE INTRINSIC VISCOSITIES OF STAR-SHAPED AND LINEAR POLYSTYRENES
    SUN, SF
    LIN, S
    SUN, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 9 - POLY
  • [24] Solution properties of star-shaped polystyrenes having peripheral charged ions
    Ishizu, K
    Kitano, H
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 229 (01) : 165 - 167
  • [25] Multi-methacrylated star-shaped, photocurable poly(methyl methacrylate) macromonomers via quasiliving ATRP with suppressed curing shrinkage
    Szanka, Amalia
    Szarka, Gyoergyi
    Ivan, Bela
    POLYMER, 2013, 54 (22) : 6073 - 6077
  • [26] Graphoepitaxy of Symmetric Six-Arm Star-Shaped Poly(methyl methacrylate)-block-Polystyrene Copolymer Thin Film
    Park, So Yeong
    Jeong, Hyeon U.
    Lee, Jaeyong
    Jang, Junho
    Kim, Sanghoon
    Choi, Chungryong
    Kim, Jaeup U.
    Kim, Jin Kon
    MACROMOLECULAR RAPID COMMUNICATIONS, 2021, 42 (19)
  • [27] Blends of poly(methyl methacrylate) and polyamides
    Carone, E
    Felisberti, MI
    Nunes, SP
    JOURNAL OF MATERIALS SCIENCE, 1998, 33 (14) : 3729 - 3735
  • [28] Blends of poly(methyl methacrylate) and polyamides
    E. Carone
    M. I. Felisberti
    S. Pereira Nunes
    Journal of Materials Science, 1998, 33 : 3729 - 3735
  • [29] Thermal degradation of star-shaped poly(ε-caprolactone)
    Xie, Wenyuan
    Gan, Zhihua
    POLYMER DEGRADATION AND STABILITY, 2009, 94 (07) : 1040 - 1046
  • [30] SYNTHESIS OF STAR-SHAPED POLY(ETHYLENE OXIDE)
    GNANOU, Y
    LUTZ, P
    REMPP, P
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1988, 189 (12): : 2885 - 2892