Peracetic Acid Mediated sp2 C-H Selenation of Arenes

被引：7
|
作者：
Hsieh, Ping-An [1 ]
Badsara, Satpal Singh [1 ,2 ]
Tsai, Chia-Hsuan [1 ]
Reddy, Daggula Mallikarjuna [1 ]
Lee, Chin-Fa [1 ]
机构：
[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
[2] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India
来源：
SYNLETT | 2016年 / 27卷 / 10期
关键词：
peracetic acid; arenes; diselenides; C-Se coupling; selenide ethers; METAL-FREE; UNSYMMETRICAL DIARYL; ENANTIOSELECTIVE ALKYLATION; ORGANOTELLURIUM COMPOUNDS; ORGANOSELENIUM COMPOUNDS; GLUTATHIONE-PEROXIDASE; SELENIUM-COMPOUNDS; COUPLING REACTIONS; PHENYL SELENIDES; ACYL RADICALS;
D O I：
10.1055/s-0035-1561408
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Peracetic acid promoted C-Se coupling reaction of arenes with diselenides under metal-free and solvent-free conditions has been described. The resulting selenide ethers were obtained in good to excellent yields. Peracetic acid provided the selenide ethers via sp(2) C-H selenation whereas previously in case of DTBP sp(3) C-H selenation was observed.
引用
收藏
页码：1557 / 1562
页数：6
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