Synthesis, photophysical and electrophosphorescent properties of a novel fluorinated rhenium(I) complex

A novel fluorinated rhenium complex, i.e., Re-BFPP (BFPP, 2, 3-bis(4-fluorophenyl)pyrazino[2,3-f][ 1,10]phenanthroline) was designed, synthesized and characterized by H-1 NMR and mass spectroscopy. The light-emitting and electrochemical properties of this complex were studied. The organic light-emitting diodes (OLEDs) employing Re-BFPP as a dopant emitter with the structures of ITO/m-MTDATA (10 nm)/NPB (20 nm)/CBP: X wt.% Re-BFPP (30 mn)/Bphen (10 nm)/Alq(3) (30 nm)/LiF(1 nm)/Al (100 nm) were successfully fabricated and a broad electroluminescent peak at 553 nm was observed. The 10 wt.% Re-BFPP doped device exhibited the maximum luminance of 6342 cd/m(2) and a peak current efficiency of 17.9 cd/A, corresponding to the power efficiency of 8.1 Im/W. (C) 2009 Elsevier B.V. All rights reserved.