Preparation and reactions of 2,4,6-tris(trifluoromethyl)phenylamine

被引：9

作者：

Ahlemann, JT

Roesky, HW

Noltemeyer, M

Schmidt, HG

Markovsky, LN

Shermolovich, YG

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-25660 Kyiv, Ukraine

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 87卷 / 01期

关键词：

aromatic fluorides; fluorinated amines; silicon derivatives;

D O I：

10.1016/S0022-1139(97)00097-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from RfH (1) [R-f=1,3,5-tris(trifluoromethyl)phenyl] RfNH2 (6) is obtained in a four-step synthesis. The amine 6 reacts with chlorotrimethylsilane in the presence of DBU (1,8-diazabicyclo(5,4,0)undec-7-ene) forming the monosilylated and the bissilylated amines 7 and 8. The potassium salt of 7 reacts with SiCl4 yielding RfN(SiCl3), (10). The single crystal X-ray structure of 10 is reported. (C) 1998 Elsevier Science S.A.

引用

页码：87 / 90

页数：4

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