Unique chains of alternating octahedral and tetrahedral cobalt(II) sites:: crystal structures of the novel chloro-bridged complexes [Co4(μ-Cl)6Cl2(thf)4(MeOH)2]n and [{Co4(μ-Cl)6Cl2(thf)4(H2O)2}•2THF]n

被引：18
|
作者：
Hierso, JC
Ellis, DD
Spek, AL
Bouwman, E
Reedijk, J
机构：
[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 15期
关键词：
D O I：
10.1039/b003213l
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Co-4(mu-Cl)(6)Cl-2(thf)(4)(MeOH)(2)](n), a catena-polycobalt(ii) complex with an unusual linear chain of octahedral/tetrahedral/octahedral cobalt sites, is obtained quantitatively from the reaction between cobalt chloride hydrate and trimethylorthoformate in THF.
引用
收藏
页码：1359 / 1360
页数：2
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