Enhancing the enantioselective recognition and sensing of chiral anions by halogen bonding

被引：65
|
作者：
Lim, Jason Y. C. [1 ]
Marques, Igor [2 ,3 ]
Ferreira, Liliana [3 ]
Felix, Vitor [2 ,3 ]
Beer, Paul D. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, Mansfield Rd, Oxford OX1 3TA, England
[2] Univ Aveiro, CICECO Aveiro Inst Mat, Dept Chem, P-3810193 Aveiro, Portugal
[3] Univ Aveiro, iBiMED Inst Biomed, Dept Med Sci, P-3810193 Aveiro, Portugal
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 32期
关键词：
AMINO-ACIDS; RECEPTORS; WATER; EXPLORATION;
D O I：
10.1039/c6cc01701k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral halogen bonding (S)-BINOL-based receptors are demonstrated to enhance the enantioselective recognition and sensing of chiral anions compared to their hydrogen bonding analogues. Computational studies attribute this behaviour to the strict linearity of halogen bonding (XB) and steric environment conferred by the XB donor groups bridged by the (S)-BINOL motif.
引用
收藏
页码：5527 / 5530
页数：4
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