Cyclic voltammetry of the electron transfer reaction between bis(cyclopentadienyl)iron in 1,2-dichloroethane and hexacyanoferrate in water

被引：5
|
作者：
Tatsumi, Hirosuke [1 ]
Katano, Hajime [1 ]
机构：
[1] Fukui Prefectural Univ, Dept Biosci, Fukui 9101195, Japan
来源：
ANALYTICAL SCIENCES | 2007年 / 23卷 / 05期
关键词：
D O I：
10.2116/analsci.23.589
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The electron transfer (ET) reaction between bis(cyclopentadienyl)iron(II) ([Fe-II(C5H5)(2)]) in 1,2-dichloroethane (1,2-DCE) and hexacyanoferrate redox couple ([Fe-II/III(CN)(6)](4-/3-)) in water (W) at the interface has been studied by using cyclic voltammetry. The voltammetric results can be explained well by a theoretical equation for the so-called IT-mechanism, in which a homogeneous ET reaction between [Fe(C5H5)(2)] (partially distributed from 1,2-DCE) and [Fe(CN)(6)](3-) takes place in the W phase and the resultant [Fe(C5H5)(2)](+) ion is responsible for current passage across the interface. The forward rate constant of the homogeneous ET reaction, [Fe(C5H5)(2)] + [Fe(CN)(6)](3-) = [Fe(C5H5)(2)](+) + [Fe(CN)(6)](4-) in W phase, k(f)(IT), was determined to be (2.9 +/- 2.2)x 10(10) M-1 s(-1), which was in good agreement with k(f)(IT) = (3.2 +/- 2.0)x 10(10) M-1 s(-1), which had been determined by using normal-pulse voltammetry.
引用
收藏
页码：589 / 591
页数：3
相关论文
共 50 条
  • [31] Electrochemical instability in the transfer of cationic surfactant across the 1,2-dichloroethane/water interface
    Kasahara, T
    Nishi, N
    Yamamoto, M
    Kakiuchi, T
    [J]. LANGMUIR, 2004, 20 (03) : 875 - 881
  • [32] Effect of the supporting electrolytes on voltammetry at liquid/liquid microinterfaces between water and nitrobenzene, 1,2-dichloroethane or 1,6-dichlorohexane
    Rimboud, Mickael
    Charreteur, Kevin
    Sladkov, Vladimir
    Elleouet, Catherine
    Quentel, Francois
    L'Her, Maurice
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2009, 636 (1-2) : 53 - 59
  • [33] Ion Transfer of Aromatic Amines on the Water/1,2-Dichloroethane Interface: Theoretical Study
    Martinez-Pacheco, Heidy
    Velazquez-Manzanares, Miguel
    Ramirez-Galicia, Guillermo
    [J]. JOURNAL OF SOLUTION CHEMISTRY, 2013, 42 (11) : 2200 - 2212
  • [34] Formal transfer potentials of strontium and uranyl ions at water|1,2-dichloroethane interfaces
    Stockmann, Tom J.
    Montgomery, Anne-Marie
    Ding, Zhifeng
    [J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2012, 90 (10): : 836 - 842
  • [35] Voltammetric determination of facilitated ion transfer across the water/1,2-dichloroethane interface
    Canan Baslak
    Tevfik Atalay
    [J]. Russian Journal of Electrochemistry, 2014, 50 : 180 - 185
  • [36] ERYTHROMYCIN TRANSFER ACROSS THE WATER 1,2-DICHLOROETHANE INTERFACE MODIFIED BY A PHOSPHOLIPID MONOLAYER
    YUDI, LM
    SANTOS, E
    BARUZZI, AM
    SOLIS, VM
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 379 (1-2): : 151 - 158
  • [37] STANDARD GIBBS ENERGIES OF TRANSFER OF UNIVALENT IONS FROM WATER TO 1,2-DICHLOROETHANE
    SABELA, A
    MARECEK, V
    SAMEC, Z
    FUOCO, R
    [J]. ELECTROCHIMICA ACTA, 1992, 37 (02) : 231 - 235
  • [38] Solvation Effect Facilitates Ion Transfer across Water/1,2-Dichloroethane Interface
    Nsabimana, Jacques
    Nestor, Uwitonze
    Girma, Girum
    Pamphile, Ndagijimana
    Zhan, Dongping
    Tian, Zhong-Qun
    [J]. CHEMELECTROCHEM, 2016, 3 (12): : 2165 - 2169
  • [39] STUDIES OF THE WATER 1,2-DICHLOROETHANE INTERFACE IMPEDANCE - EFFECT OF TRANSFER OF THE TETRAMETHYLAMMONIUM ION
    FIGASZEWSKI, Z
    PALESKA, I
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 266 (02) : 253 - 264
  • [40] Effect of phospholipids on the kinetics of dioxygen transfer across a 1,2-dichloroethane/water interface
    Strutwolf, J
    Zhang, J
    Barker, AL
    Unwin, PR
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (24) : 5553 - 5558
12345